A triclinic polymorph of (E)-2-(4-isobutylphenyl)-N′-[1-(4-nitrophenyl)ethylidene]propanohydrazide
نویسندگان
چکیده
The asymmetric unit of the triclinic polymorph of the title compound, C21H25N3O3, consists of two mol-ecules, whereas for the monoclinic polymorph Z' = 1 [Fun et al. (2009 ▶). Acta Cryst. E65, o445]. The two mol-ecules exhibit an E configuration with respect to the C=N bond. The mol-ecules are linked into dimers by N-H⋯O and C-H⋯O hydrogen bonds forming R 2 (2)(8) ring motifs. In addition, π-π inter-actions occur between nitro-phenyl groups [minimum centroid-centroid distance 3.940 (2) Å], stacking the molecules along the ac plane.
منابع مشابه
Space group revsion of the triclinic polymorph of salicylaldehyde azine
The structure of the title compound, C(14)H(12)N(2)O(2) {systematic name: 2,2'-[hydrazinediylidenebis(methanylyl-idene)]diphen-ol}, has already been determined in the triclinic space group P[Formula: see text] with Z = 4 [El-Medani, Aboaly, Abdalla & Ramadan (2004 ▶). Spectrosc. Lett.37, 619-632]. However, the correct space group should be P2(1)/c with Z = 4. This structure is a new polymorph o...
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